+3 votes
in Chemistry by kratos

Adsorption of a gas on surface of solid is generally accompanied by a decrease in entropy, still it is a spontaneous process. Explain.

1 Answer

+4 votes
by kratos
 
Best answer

△S = -ve but △H is also negative due to attraction. △G = △H - T△S, △G can be negative if △H has sufficiently high negative value as - T△S is positive. So, in adsorption process, a combination of these two factors makes △G negative.

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