I think Charge on the smaller sphere is 10 microcoulomb.
Explanation:
As we know that after connecting the wire the potential of both the sphere will be equal.
Let q1 and q2 be the charge on small and large spheres respectively
Also, q1 + q2 = 30 micro columb (before and after connecting the wire.
Now the shortcut
V1 = V2
Kq1/r1 = Kq2/r2
q1/5 = q2/ 10
2q1 = (30 - q1)
q1 = 10 micro columb