The correct option is: (B) 4 eV
Explanation:
To transition to the –12eV state with only two photon emissions, the only options are for the electron to make the following transitions: –1eV → – 3eV → –12eV giving us photons of energy 2eV and 9eV or –1eV → – 7 eV → – 12eV giving photons of energy 6eV and 5eV . This means that the 4 eV photon is not possible with only two transitions.