State one observation for each of the following :
(i) Excess ammonium hydroxide solution is added to lead nitrate solution.
(ii) Bromine vapours are passed into a solution of ethyne in carbon tetrachloride.
(iii) A zinc granule is added to copper sulphate solution.
(iv) Zinc nitrate crystals are strongly heated.
(v) Sodium hydroxide solution is added to ferric chloride solution at first a little and then in excess.