State observation for each of the following :
i. Excess ammonium hydroxide solution is added to lead nitrate solution.
ii. Bromine vapors are passed into a solution of ethyne in carbon tetrachloride.
iii. A zinc granule is added to copper sulphate solution.
iv. Zinc nitrate crystals are strongly heated.
v. Sodium hydroxide solution is added to ferric chloride solution at first a little and then in excess