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in JEE by kratos

Calculate the percentage of compounds obtained by monobromination of isobutene. The relative reactivity of 1, 2, 3 H atoms to bromination is 1: 82: 1600.

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by kratos
 
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Reactivity order of bromination = 3° : 2° : 1° = 1600 : 82 : 1

(A) is obtained from the reaction of none equivalent 1° H atoms.

(B) is obtained from the reaction of one 3° H atoms

Percentage of (A) (isobutyl bromide) 9 x 100/1609 = 0.56%

Percentage of (B) (tert-butyl bromide) = 1600 x 100/1609 = 99.4%

Ratio = 177.7:1

Formation of t-Butyl bromide is 177.7 times to that of Isobutyl bromide.

Relative amount 9 x 1

1600 x 1 = 1600.0

Total = 1609.0

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