The correct option is (b) 100 ohm.
Explanation:
When C is removed circuit becomes RL circuit hence tan π/3 = XL/R ......(i)
When L is removed circuit becomes RC circuit hence tan π/3 = XC/R ......(ii)
From equation (i) and (ii) we obtain XL = XC. This is the condition of resonance and in resonance Z = R = 100Ω.