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in Chemistry by kratos

Derive Bragg'* equation.

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by kratos
 
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*Derivation of Bragg' equation :** When X-rays are incident on the crystal or plane, they are diffracted from the lattice points (lattice points may be atoms or ions or molecules). In the crystal the lattice points are arranged in regular pattern. When the waves are diffracted from these points, the waves may be constructive or destructive interference.

The 1st and 2nd waves reach the crystal surface. They undergo constructive interference. Then from the figure 1st and 2nd rays are parallel waves. So, they travel the same distance till the wave form AD. The second ray travels more than the first by an extra distance (DB + BC) after crossing the grating for it to interfere with the first ray in a constructive manner. Then only they can be in the same phase with one another. If the two waves are to be in phase, the path difference between the two ways must be equal to the wavelength (λ) or integral multiple of it (n λ, where n = 1, 2, 3, .....)

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