32 gm of sulphur contain = 6.023 x 1023 atoms
3.2 gm of sulphur contain = (6.023 x 1023)/32 x 3.2 = 6.023 x 1022
Now, 6.023 x 1023 atom of calcium have mass = 40 g
6.023 x 1022 atoms of calcium have mass = 40/(6.023 x 1023) x (6.023 x 1022) = 4 g
Hence, the mass of calcium is 4 g.