SO2,NO2 gases are released into the atmosphere from various sources. These dissolve in rain water to give acid which corrodes marble statues
2SO2+ O2 → 2SO3
H2O + SO3 → H2SO4
2NO2+ H2O → 2HNO3
CaCO3+ H2SO4→ CaSO4 + H2O + CO2
CaCO3+ 2HNO3 → Ca(NO3)2+ H2O + CO2